https://phys.org/news/2018-05-solubility-problemmechanochemistry-solution.html

It may seem paradoxal to imagine that the destructive forces of a ball mill can help creating complex molecules. However, Borchardt and his team have done just that. Highly aromatic molecular systems (highly aromatic in chemistry means systems with a high number of conjugated bonds that are very stable) such as nanographenes are known for their poor solubility. Therefore, they are difficult to synthesize in traditional chemical methods, which require a solvent. The Borchardt group exclusively works with the intense mechanical forces of ball mills. The huge forces in the mills initiate a chemical reaction in which a hexaphenylbenzene precursor is converted into a completly aromatic system. Not only does this method represent a much simpler, safer and more sustainable alternative to conventional chemical syntheses, it also opens up new ways: "We can also broaden the feasibility of this famous reaction towards molecules that are insoluble, " explains Borchardt.

The TUD scientists managed to synthesize the triangular shaped C60 as well as C222 benchmark nanographenes within very short time and with comparably little effort. Now they continue their mechanochemical research with the aim of producing even larger molecules such as graphene nanoribbons which are adaptable for application. The recent findings of the Borchardt group will certainly contribute new aspects to the search for new electronic and solar energy material and also to resolving some of the hindrances of chemical synthesis by eliminating solvents.

                                                            
                                    
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